Which AWS service or feature will meet this requirement?

Explanations:

Amazon Connect is a cloud-based contact center service that does not provide direct private network connections between AWS and corporate networks. It is focused on customer engagement and communication, not network connectivity.

Amazon Route 53 is a scalable domain name system (DNS) web service used for domain registration and routing internet traffic to resources. It does not facilitate private network connections between AWS and on-premises networks.

AWS Direct Connect is a service that enables customers to establish a dedicated network connection from their premises to AWS. It provides a reliable and consistent performance for transferring data and can reduce bandwidth costs. This service is specifically designed for creating private network connections.

VPC peering allows the connection of two VPCs (Virtual Private Clouds) within AWS, enabling them to communicate as if they are on the same network. However, it does not connect an AWS VPC to a corporate network, thus not meeting the requirement for establishing a private connection between AWS and a corporate network.